Spectrum adapted expectation-conditional maximization algorithm for extending high–throughput peak separation method in XPS analysis

نویسندگان

چکیده

We introduced the spectrum-adapted expectation-conditional maximization (ECM) algorithm to improve efficiency of peak fitting spectral data by various models. The ECM can perform using Pseudo–Voigt mixture model and Doniach–Šunjić–Gauss which are generally used for in X-ray photoelectron spectroscopy. Analyses synthetic experimental showed that proposed method quickly completed calculation estimated well-fitted curves data. This result suggests spectrum adapted efficiently large number sets.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

The dynamic ‘expectation–conditional maximization either’ algorithm

The ‘expectation–conditional maximization either’ (ECME) algorithm has proven to be an effective way of accelerating the expectation–maximization algorithm for many problems. Recognizing the limitation of using prefixed acceleration subspaces in the ECME algorithm, we propose a dynamic ECME (DECME) algorithm which allows the acceleration subspaces to be chosen dynamically. The simplest DECME im...

متن کامل

Expectation Maximization Deconvolution Algorithm

In this paper, we use a general mathematical and experimental methodology to analyze image deconvolution. The main procedure is to use an example image convolving it with a know Gaussian point spread function and then develop algorithms to recover the image. Observe the deconvolution process by adding Gaussian and Poisson noise at different signal to noise ratios. In addition, we will describe ...

متن کامل

The Expectation Maximization Algorithm

This note represents my attempt at explaining the EM algorithm (Hartley, 1958; Dempster et al., 1977; McLachlan and Krishnan, 1997). This is just a slight variation on TomMinka’s tutorial (Minka, 1998), perhaps a little easier (or perhaps not). It includes a graphical example to provide some intuition. 1 Intuitive Explanation of EM EM is an iterative optimizationmethod to estimate some unknown ...

متن کامل

Rigid Point Registration with Expectation Conditional Maximization

This paper addresses the issue of matching rigid 3D object points with 2D image points through point registration based on maximum likelihood principle in computer simulated images. Perspective projection is necessary when transforming 3D coordinate into 2D. The problem then recasts into a missing data framework where unknown correspondences are handled via mixture models. Adopting the Expectat...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Science and Technology of Advanced Materials: Methods

سال: 2021

ISSN: ['2766-0400']

DOI: https://doi.org/10.1080/27660400.2021.1899449